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Abstract Geopolymers, a class of alkali‐activated binders, are studied as sustainable alternatives to Ordinary Portland Cement due to their potential for CO₂emission reduction. However, the critical relationship between early‐age reaction kinetics, the development of material properties, and evolving chemical structure remains insufficiently explored, primarily because of the complexity of the underlying chemical reactions and the wide variety of geopolymer chemistries. To address this, we investigate the mechanism of early‐age (<72 h) strength development of a model metakaolin geopolymer by measuring curing kinetics using isothermal calorimetry, material property development via rheology, and chemical coordination at distinct extents of reaction via²⁹Si and²⁷Al NMR. A novel approach of collecting solid‐state²⁹Si and²⁷Al NMR spectra at low temperature (−17°C) successfully quenches the geopolymer reaction, allowing for spectrum collection at a desired extent of reaction despite long²⁹Si NMR spectrum collection times. Applying the Avrami kinetic model to deconvoluted calorimetry data enables independent analysis of dissolution and polycondensation/crosslinking reactions. From these data, the gel reaction product mass fraction is estimated, revealing an exponential relationship with the storage modulus in the activated metakaolin slurry. This study provides new insights into the interconnected dynamics of molecular chemistry, reaction kinetics, rheology, and strength development, offering a semi‐empirical framework for understanding property evolution in geopolymers more broadly. 

Predicting the response of complex fluids to different flow conditions has been the focal point of rheology and is generally done via constitutive relations. There are, nonetheless, scenarios in which not much is known from the material mathematically, while data collection from samples is elusive, resource-intensive, or both. In such cases, meta-modeling of observables using a parametric surrogate model called multi-fidelity neural networks (MFNNs) may obviate the constitutive equation development step by leveraging only a handful of high-fidelity (Hi-Fi) data collected from experiments (or high-resolution simulations) and an abundance of low-fidelity (Lo-Fi) data generated synthetically to compensate for Hi-Fi data scarcity. To this end, MFNNs are employed to meta-model the material responses of a thermo-viscoelastic (TVE) fluid, consumer product Johnson’s® Baby Shampoo, under four flow protocols: steady shear, step growth, oscillatory, and small/large amplitude oscillatory shear (S/LAOS). In addition, the time–temperature superposition (TTS) of the material response and MFNN predictions are explored. By applying simple linear regression (without induction of any constitutive equation) on log-spaced Hi-Fi data, a series of Lo-Fi data were generated and found sufficient to obtain accurate material response recovery in terms of either interpolation or extrapolation for all flow protocols except for S/LAOS. This insufficiency is resolved by informing the MFNN platform with a linear constitutive model (Maxwell viscoelastic) resulting in simultaneous interpolation and extrapolation capabilities in S/LAOS material response recovery. The roles of data volume, flow type, and deformation range are discussed in detail, providing a practical pathway to multifidelity meta-modeling of different complex fluids. 

Electron transport in complex fluids, biology, and soft matter is a valuable characteristic in processes ranging from redox reactions to electrochemical energy storage. These processes often employ conductor–insulator composites in which electron transport properties are fundamentally linked to the microstructure and dynamics of the conductive phase. While microstructure and dynamics are well recognized as key determinants of the electrical properties, a unified description of their effect has yet to be determined, especially under flowing conditions. In this work, the conductivity and shear viscosity are measured for conductive colloidal suspensions to build a unified description by exploiting both recent quantification of the effect of flow-induced dynamics on electron transport and well-established relationships between electrical properties, microstructure, and flow. These model suspensions consist of conductive carbon black (CB) particles dispersed in fluids of varying viscosities and dielectric constants. In a stable, well-characterized shear rate regime where all suspensions undergo self-similar agglomerate breakup, competing relationships between conductivity and shear rate were observed. To account for the role of variable agglomerate size, equivalent microstructural states were identified using a dimensionless fluid Mason number, ${\mathit{Mn}}_f$, which allowed for isolation of the role of dynamics on the flow-induced electron transport rate. At equivalent microstructural states, shear-enhanced particle–particle collisions are found to dominate the electron transport rate. This work rationalizes seemingly contradictory experimental observations in literature concerning the shear-dependent electrical properties of CB suspensions and can be extended to other flowing composite systems. 

An investigation of high-transverse-momentum (high- $p_T$) photon-triggered jets in proton-proton ( $p\text{−}p$) and ion-ion ( $A\text{−}A$) collisions at $\sqrt{s_{NN}}=0.2$and $5.02\mathrm{TeV}$is carried out, using the multistage description of in-medium jet evolution. Monte Carlo simulations of hard scattering and energy loss in heavy-ion collisions are performed using parameters tuned in a previous study of the nuclear modification factor ( $R_{AA}$) for inclusive jets and high- $p_T$hadrons. We obtain a good reproduction of the experimental data for photon-triggered jet $R_{AA}$, as measured by the ATLAS detector, the distribution of the ratio of jet to photon $p_T$( $X_{J\gamma }$), measured by both CMS and ATLAS, and the photon-jet azimuthal correlation as measured by CMS. We obtain a moderate description of the photon-triggered jet $I_{AA}$, as measured by STAR. A noticeable improvement in the comparison is observed when one goes beyond prompt photons and includes bremsstrahlung and decay photons, revealing their significance in certain kinematic regions, particularly at $X_{J\gamma }>1$. Moreover, azimuthal angle correlations demonstrate a notable impact of bremsstrahlung photons on the distribution, emphasizing their role in accurately describing experimental results. This work highlights the success of the multistage model of jet modification to straightforwardly predict (this set of) photon-triggered jet observables. This comparison, along with the role played by bremsstrahlung photons, has important consequences on the inclusion of such observables in a future Bayesian analysis. Published by the American Physical Society2025 

The Collaboration reports a new determination of the jet transport parameter $\hat{q}$in the quark-gluon plasma (QGP) using Bayesian inference, incorporating all available inclusive hadron and jet yield suppression data measured in heavy-ion collisions at the BNL Relativistic Heavy Ion Collider (RHIC) and the CERN Large Hadron Collider (LHC). This multi-observable analysis extends the previously published Bayesian inference determination of $\hat{q}$, which was based solely on a selection of inclusive hadron suppression data. is a modular framework incorporating detailed dynamical models of QGP formation and evolution, and jet propagation and interaction in the QGP. Virtuality-dependent partonic energy loss in the QGP is modeled as a thermalized weakly coupled plasma, with parameters determined from Bayesian calibration using soft-sector observables. This Bayesian calibration of $\hat{q}$utilizes active learning, a machine-learning approach, for efficient exploitation of computing resources. The experimental data included in this analysis span a broad range in collision energy and centrality, and in transverse momentum. In order to explore the systematic dependence of the extracted parameter posterior distributions, several different calibrations are reported, based on combined jet and hadron data; on jet or hadron data separately; and on restricted kinematic or centrality ranges of the jet and hadron data. Tension is observed in comparison of these variations, providing new insights into the physics of jet transport in the QGP and its theoretical formulation. Published by the American Physical Society2025